## Abstract A new band at 896 cm^−1^ is ascribed to a local mode, __v__~1~, due to a molybdate ion occupying a cation vacancy. Local modes for __v__~3~ and __v__~4~ were also found at __ca.__ 800 and 397 cm^−1^, respectively. The relative intensity for translational modes at 71 and 59 cm^−1^ varied
Fabrication and characterization of humidity sensor based on (Li2MoO4)x(CaMoO4)1−x system
✍ Scribed by Il Jin Kim; Sang Do Han; Hi Deok Lee; Jin Suk Wang; Ishwar Singh; S.V. Kornilov
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 144 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0921-5107
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✦ Synopsis
The characteristics of a humidity sensor using a water-soluble and a single crystal material with composition (Li 2 MoO 4 ) x (CaMoO 4 ) 1-x , where x is 0.8-0.9 have been studied in detail. The fabrication technology has been developed for a low humidity sensor. The specific procedures with the use of polystyrol and teflon combination as protective layer have been developed for technological sensors by microelectronics techniques. The logarithm of the sensor conductance log σ is linear decreasing function of ratio log 2 (C s /C), where C s is the concentration of saturated water vapours and C is the concentration of water vapours to be detected up to 8000 ppm.
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When heated to elevated temperatures ( \(>250^{\circ} \mathrm{C}\) ), the chromium titanium oxides \(\mathrm{Cr}_{2-y} \mathrm{Ti}_{y} \mathrm{O}_{3+x}\) displayed p-type semiconducting behaviour giving a resistance increase upon exposure to reducing gases. The materials show a very strong and fast