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F-Element/crown ether complexes. 10. Oxidation of uranium tetrachloride to tetrachlorodioxouranate(2-) in the presence of crown ethers: structural characterization of crown ether complexed ammonium ions

✍ Scribed by Rogers, Robin D.; Kurihara, Lynn K.; Benning, Matthew M.


Book ID
121085182
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
931 KB
Volume
26
Category
Article
ISSN
0020-1669

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The host-guest complexation and the kinetics of the thermal dediazoniation of benzenediazonium tetrafluoroborate in the presence of unsubstituted and (di)benzene-and dicyclohexane-substituted crown ethers containing 4-10 oxygen atoms were studied by UV spectrophotometry in 1,2-dichloroethane at 40Β°C