Extrusion Monitoring of Polymer Melts Using a High-Temperature Surface-NMR Probe

✍ Scribed by Antje Gottwald; Ulrich Scheler

• Publisher: John Wiley and Sons
• Year: 2005
• Tongue: English
• Weight: 156 KB
• Volume: 290
• Category: Article
• ISSN: 1438-7492
• DOI: 10.1002/mame.200400246

✦ Synopsis

Abstract

Summary: Extrusion is one of the major ways of polymer processing, and extrusion monitoring is important to control or improve the extrusion process and the product quality. Especially methods for in‐line monitoring are desired because those enable the fastest possible response and a localization of chemical reactions in reactive processing. Methods of optical and acoustic spectroscopy have successfully been implemented so far. NMR provides a wealth of information. Surface NMR mostly gives access to molecular mobility via relaxation times. These can be correlated to temperature, composition and homogeneity which are substantial indicators for the product quality. NMR is a non‐destructive method, which does not require direct contact with the sample and it is not restricted to optical transparent materials and is therefore suitable for extrusion monitoring. The problem for the adaptation is the hostile environment in and in front of an extruder for polymer melts. Here, a NMR surface probe is presented sustaining this environment in front of an extruder. First measurements with this device are shown.

High‐temperature surface‐NMR probe.

magnified imageHigh‐temperature surface‐NMR probe.