✦ LIBER ✦
External spin—orbit coupling. The T1 state of naphthalene in a dibromobenzene host cyrstal
✍ Scribed by Steven D. Colson; Bruce W. Gash
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 132 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The origin of the Tl state of naphthalene in a p-dibromobenzene host crystal is shown to be the strongest line in the spectrum at 20720.9 cm -1 . The vibronic activity of the naphthalene phosphorescence indicates that a spin-orbit coupling mechanism different from the one vibronically induced in an isotopic mixed naphthalene crystal is active in a chemically mixed crystal with a halogen-containing host.