For metal(II1) [M(III)] S-sulphoquinolin-%olates, systematic studies of the atomic number effect in complexes exhibiting ligand fluorescence were carried out in aqueous solution. The fluorescence lifetimes of various chelates were investigated as a function of complexed metal ion, pH and metal-to-li
External Heavy-Atom Effect on the Prompt and Delayed Fluorescence of [70]Fullerenes
✍ Scribed by Dr. Carlos Baleizão; Prof. Dr. Mário N. Berberan-Santos
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 353 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1439-4235
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Static second hyperpolarizabilities were calculated for molecules including tetrahydrofuran homologs by ab initio molecular orbital methods at the Hartree᎐Fock and various correlation levels. Substitution of the heteroatom with a heavier atom is found to be effective for increase of the second hyper
## Abstract We have synthesized ruthenium(II)– and osmium(II)–polypyridyl complexes ([M(bpy)~2~**L**]^2+^, in which M=Os^II^ or Ru^II^, bpy=2,2′‐bipyridyl, and **L**=4‐(2,2′‐bipyridinyl‐4‐yl)benzene‐1,2‐diol) and studied the interfacial electron‐transfer process on a TiO~2~ nanoparticle surface usi