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External heavy atom effect on decay of the triplet state of aromatic hydrocarbons. I. The decay functions of phosphorescence and of the population of the triplet state

โœ Scribed by Jan Najbar


Book ID
107796692
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
373 KB
Volume
11
Category
Article
ISSN
0022-2313

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โœ F. Metz; S. Friedrich; G. Hohlneicher ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 470 KB

It is shown that in sromntic hydrocsrbons the ISC rate constants (7';-S0) ;?re governed by HT vibronic coupling. Some established rules for deciding between different coupling mechanisms are proved to be invalid. Application to naphthalene yields excellent agreement \iih esperimcnta! results.