Dynamics following photoexcitation into S 1 of chromophoric thiacyanine (TC) in mixed Langmuir-Blodgett films is affected by an applied electric field, and fluorescence quantum yield of TC is changed by an external electric field. The field dependence of fluorescence is more enhanced in an associate
External electric field effects on absorption and fluorescence spectra of indocarbocyanine in Langmuir-Blodgett films
β Scribed by Nobuhiro Ohta; Yoshiaki Ogata; Shigetoshi Okazaki; Iwao Yamazaki
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 523 KB
- Volume
- 244
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The change in electric dipole moment and molecular polarizability of indocarbocyanine (ICC) in Langmuir-Blodgett films upon excitation into Sj is estimated to be 5.3 Γ 10 -32 C m (0.016 D) and 3.5 x 10 -40 J-~ C 2 m 2 (3.1 in units of 4'rre o A~). respectively, based on the electroabsorption spectra. A directional nonradiative process in S~ of ICC is also shown to be affected by an external electric field, based on the electrofluorescence spectra combined with the electroabsorption spectra.
π SIMILAR VOLUMES
Pseudo-Stark splittings have been measured for optical transitions of V\*, Cr3+ and Co3\* in corundum (cr-AlaO3) when these crystals are submitted to dc and ac fields. Quantitative results have been obtained for dc electric field parallel to the C3-axis. With the electric field perpendicular to the