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External electric field effects on absorption and fluorescence spectra of indocarbocyanine in Langmuir-Blodgett films

✍ Scribed by Nobuhiro Ohta; Yoshiaki Ogata; Shigetoshi Okazaki; Iwao Yamazaki


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
523 KB
Volume
244
Category
Article
ISSN
0009-2614

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✦ Synopsis


The change in electric dipole moment and molecular polarizability of indocarbocyanine (ICC) in Langmuir-Blodgett films upon excitation into Sj is estimated to be 5.3 Γ— 10 -32 C m (0.016 D) and 3.5 x 10 -40 J-~ C 2 m 2 (3.1 in units of 4'rre o A~). respectively, based on the electroabsorption spectra. A directional nonradiative process in S~ of ICC is also shown to be affected by an external electric field, based on the electrofluorescence spectra combined with the electroabsorption spectra.


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