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Extending the Reaction Landscape of the {Pt(μ-S)2Pt} Core: From Metal Centers to Non-Metallic Electrophiles

✍ Scribed by Pilar Gonzalez-Duarte; Agusti Lledos; Ruben Mas-Balleste

Publisher
John Wiley and Sons
Year
2004
Weight
9 KB
Volume
35
Category
Article
ISSN
0931-7597

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Extending The Reaction Landscape of the
Extending The Reaction Landscape of the {Pt(μ-S)2Pt} Core: From Metal Centers to Non-Metallic Electrophiles
✍ Pilar González-Duarte; Agustí Lledós; Rubén Mas-Ballesté 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB

## Abstract The outstanding nucleophilicity of the {Pt(μ‐S)~2~Pt} core in compounds [L~2~Pt(μ‐S)~2~PtL~2~] (L~2~ = phosphane) accounts for their ability to act as metalloligands towards main group and transition metals, and thus for the high number of [{L~2~Pt(μ~3~‐S)~2~PtL~2~}~__x__~ML′~__y__~]^__