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Extending the {(Mo)Mo5}12M30 Capsule Keplerate Sequence: A {Cr30} Cluster of S=3/2 Metal Centers with a {Na(H2O)12} Encapsulate

✍ Scribed by Ana Maria Todea; Alice Merca; Hartmut Bögge; Joris van Slageren; Martin Dressel; Larry Engelhardt; Marshall Luban; Thorsten Glaser; Marc Henry; Achim Müller


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
290 KB
Volume
119
Category
Article
ISSN
0044-8249

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Extending the {(Mo)Mo5}12M30 Capsule Kep
✍ Ana Maria Todea; Alice Merca; Hartmut Bögge; Joris van Slageren; Martin Dressel; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB

In previous work it was shown that molybdenum oxide based spherical hollow clusters of the type {(Mo)Mo 5 } 12 {linker} 30which, because of their structural features, are also called Keplerates-can be directly synthesized by the addition of linkers, such as V IV O 2+ and Fe III , to a dynamic librar