Extended Interactions between Metal Ions. in Transition Metal Complexes

✍ Scribed by Leonard V. Interrante (Eds.)

• Publisher: American Chemical Society
• Year: 1974
• Tongue: English
• Leaves: 415
• Series: ACS Symposium Series 5
• Category: Library

✦ Synopsis

Content: Extended interactions in transition metal oxides and chalcogenides / Aaron Wold --
High temperature crystal chemistry of V₂O₃ through the metal-insulator transition and of (Cr₀.₀₁V₀.₉₉)₂O₃, an insulator / William R. Robinson --
Synthesis and properties of some new organic intercalation complexes of tantalum sulfide / R.L. Hartless and A.M. Trozzolo --
Intermolecular magnetic exchange interactions in molecular crystals / J.M. Grow and H.H. Wickman --
Computation of field-swept EPR spectra for systems with large interelectronic interactions / R.L. Belford, P.H. Davis, G.G. Belford, and T.M. Lenhardt --
Multisite magnetic interactions in hexaurea-metal(III) halide lattices / Phillip H. Davis and R.L. Belford --
Polymeric, mixed-valence transition metal compounds / Gilbert M. Brown, Robert W. Callahan, Eugene C. Johnson, Thomas J. Meyer, and Tom Ray Weaver --
Exchange interactions in nickel(II), copper(II), and cobalt(II) dimers bridged by small anions / David N. Hendrickson and D. Michael Duggan --
Structural and magnetic properties of chromium(III) dimers / Derek J. Hodgson --
Superexchange interactions in copper(II) complexes / William E. Hatfield --
Electronic and magnetic properties of linear chain complexes derived from biscyclopentadienyl titanium(III) and of the infinite RMX₃ linear chain complexes / D. Sekutowski, R. Jungst, and G.D. Stucky --
Optical properties of linear chains / S.L. Holt --
Spectroscopic and magnetic properties of CsMI₃ type transition metal iodides --
G.L. Mcpherson and L.J. Sindel --
Magnetic and thermal properties of the linear chain series [(CH₃)₃NH] MX₃·2H₂O / J.N. Mcelearney, G.E. Shankle, D.B. Losee, S. Merchant, and R.L. Carlin --
The ferromagnetic ordering of ferrous chloride polymers of diimine ligands / W.M. Reiff, B. Dockum, C. Torardi, S. Foner, R.B. Frankel, and M.A. Weber --
The unusual magnetic properties of an imidazolate bridged polymer of an iron(III) hemin / Irwin A. Cohen and David Ostfeld --
Local and collective states in single and mixed valency chain compounds / P. Day --
Evidence for extended interactions between metal atoms from electronic spectra of crystals with square complexes / Don S. Martin, Jr. --
The nature of the lowest-energy allowed electronic transition in crystals of certain d⁸ transition metal complexes that possess extended metal chains / Basil G. Anex --
The single crystal polarized reflectance spectra and electronic structures of Rh(CO)₂acac and Ir(CO)₂acac / Thomas A. Dessent, Richard A. Palmer, and Sally M. Horner --
Directed synthesis of linear chain metal complexes with well-defined cooperative properties / R. Aderjan, D. Baumann, H. Endres, W. Gitzel, H.J. Keller, R. Lorentz, W. Moroni, M. Megnamisi-Bélombé, D. Nöthe, and H.H. Rupp --
Magnus green salt solid solutions containing mixed-valence platinum chains : an approach to 1-D metals / B.A. Scott, R. Mehran, B.D. Silverman, and M.A. Ratner --
Studies on some 1-D metal Group VIII complexes / K. Krogmann and H.P. Geserich --
Some comments on the electronic structure of Krogmann salts and the stability of Pt 2.3 / Aaron N. Bloch and R. Bruce Weisman --
The Peierls transition in one-dimensional solids / H.R. Zeller and P. Brüesch --
The preparation of and the anisotropic dielectric properties of K₂Pt(CN)₄Br₀.₃₀ · 3H₂O / R.B. Saillant and R.C. Jaklevic --
A SCF-X[alpha]-SW investigation of solid state interactions in Pt(CN)₄n- complexes / L.V. Interrante and R.P. Messmer --
One-dimensional and pseudo-one-dimensional molecular crystals / Ulrich T. Mueller-Westerhoff and Friedrich Heinrich.

✦ Table of Contents

Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
Literature Cited......Page 6
1 Extended Interactions in Transition Metal Oxides and Chalcogenides......Page 8
Literature Cited......Page 22
2 High Temperature Crystal Chemistry of V2O3 through the Metal-Insulator Transition and of (Cr0.01 V0.99)2O3, an Insulator......Page 23
Results......Page 24
Acknowledgements.......Page 28
Literature Cited.......Page 29
3 Synthesis and Properties of Some New Organic Intercalation Complexes of Tantalum Sulfide......Page 30
Results and Discussion......Page 31
Summary......Page 38
Literature Cited......Page 39
Acknowledgment......Page 40
Discussion......Page 41
Literature Cited......Page 46
1. Introduction......Page 47
2. Eigenfield Equations for Exact Calculation......Page 48
3. Frequency-Shift Perturbation......Page 52
Literature Cited.......Page 57
Structural Background......Page 58
Interactions in Cr(urea) 6X3......Page 61
Additional Studies of Interactions in M(urea) 6X3 Lattices......Page 70
Literature Cited......Page 72
Strong, Chemically-Significant Interactions Through a Bridging Ligand. μ-οxο-Bridged Complexes of Ruthenium (III).......Page 73
Weak Metal-Metal Interactions in Ligand-Bridged Ruthenium Complexes.......Page 75
The Effects of Weak Metal-Metal Interactions in Polymeric, Ligand-Bridged Compounds.......Page 78
Literature Cited......Page 82
Introduction......Page 83
Nickel(II) Dimers......Page 84
Copper(II) Dimers......Page 91
Cobalt(II) and Manganese(II) Dimers......Page 97
Literature Cited......Page 100
Introduction......Page 101
Glycinato Complex......Page 102
Phenanthroline Complexes......Page 104
Oxalato Complex......Page 106
Interpretation......Page 108
Literature Cited......Page 113
10 Superexchange Interactions in Copper(II) Complexes......Page 115
A. Structural and Magnetic Data.......Page 116
B. Correlation of Structural and Magnetic Properties.......Page 125
C. Rationalization in Terms of a Molecular Orbital Model.......Page 127
A. Structural and Magnetic Data.......Page 131
III. The Polymeric Compound [Cu(pyrazine)(NO3)2]n and Related Chains.......Page 139
V. Literature Cited......Page 145
Biscyclopentadienyl Titanium Derivatives......Page 149
RMX3 Complexes......Page 161
Literature Cited......Page 169
12 Optical Properties of Linear Chains......Page 171
Literature Cited......Page 188
13 Spectroscopic and Magnetic Properties of CsMI3 Type Transition Metal Iodides......Page 189
Literature Cited......Page 199
Crystal Structures......Page 201
Properties of [(CH3) 3NH]CoX3·2H2O (X=Cl, Br)......Page 203
Properties of [(CH3) 3NH]MnX3·2H2O (X=Cl, Br)......Page 206
Literature Cited......Page 211
Introduction......Page 212
Chemical Preparation......Page 213
Susceptibility and Magnetization Studies......Page 214
Mössbauer Studies......Page 218
Molecular Structure Studies......Page 220
Magnetic Behavior and Structure......Page 225
Literature Cited......Page 226
Acknowledgements......Page 227
16 The Unusual Magnetic Properties of an Imidazolate Bridged Polymer of an Iron(III) Hemin......Page 228
Literature Cited......Page 239
1. Introduction......Page 241
2. Localized and Collective States......Page 242
3. Types of Transition Metal Chain Compound......Page 243
4. Single Valence Metal Chain Compounds......Page 246
5. Mixed Valence Metal Chain Compounds......Page 253
Literature Cited......Page 259
Introduction......Page 261
K2PtBr4 and K2PtCl4: Minimum Extended Interactions......Page 264
Magnus1 Green Salt. Pt(NH3)4PtCl4.......Page 268
Pt2Br62- Spectra......Page 271
Pt(en)Cl2 and Pt(en)Br2. Transitions to Ionic States......Page 273
Summary......Page 280
Literature Cited......Page 282
Abstract......Page 283
Introduction......Page 284
Specular Reflection Spectroscopy......Page 285
The Glyoximates......Page 289
The Magnus' Salts......Page 292
Tetrachloroplatinate(II) Ion and Related Systems......Page 295
Characterization of the Excited State......Page 298
General Discussion......Page 302
Acknowledgment:......Page 305
Literature Cited......Page 307
Introduction......Page 308
The Electronic Structure of Planar d8 Complexes......Page 309
Results and Discussion......Page 311
Literature Cited......Page 320
I. Introduction......Page 321
II. Electronic structure of suitable metal complexes......Page 322
IV. Choice of suitable transition metal compounds......Page 325
V. Systematic Variation of Ligand Parameters......Page 326
VI. Preparation of "Mixed Valence" Solids......Page 331
Acknowledgements......Page 335
"Literature Cited,"......Page 336
Introduction......Page 338
Materials Preparation......Page 343
Experimental Results......Page 344
Discussion......Page 350
Literature Cited......Page 355
23
Studies on Some 1-D Metal Group VIII Complexes......Page 357
Literature Cited......Page 362
I. Introduction......Page 363
II. General Remarks......Page 364
III. Band-Structure Energy UB in the Tight-Binding Model......Page 366
IV. Beyond the Tight-Binding Approximation......Page 370
V. The Covalent Energy UC......Page 373
VI. Electrochemical Oxidation of Crystalline K2Pt(CN)4 to a Solid-State Galvanic Cell......Page 374
VII. Summary and Conclusions......Page 375
Literature Cited......Page 376
Acknowledgments......Page 378
25 The Peierls Transition in One-Dimensional Solids......Page 379
References......Page 382
26 The Preparation of and the Anisotropic Dielectric Properties of K2Pt(CN)4Br0.30·3H2O......Page 383
Literature Cited......Page 387
Introduction......Page 389
Method of Calculation......Page 390
Results and Discussion......Page 391
Acknowledgments......Page 397
Literature Cited......Page 398
One-dimensional Systems......Page 399
Organic Linear Systems......Page 400
Transition Metal Complexes and TCNQ Salts......Page 401
Pseudo-One-Dimensional Systems......Page 403
The STEP Arrangement......Page 405
The LADDER Arrangement......Page 407
Literature Cited......Page 408
C......Page 410
I......Page 411
M......Page 412
R......Page 413
T......Page 414
Ζ......Page 415