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Extended Fe4 butterfly complexes: theoretical analysis of magnetic properties and magnetostructural maps

✍ Scribed by Gomez-Coca, Silvia; Cauchy, Thomas; Ruiz, Eliseo


Book ID
121217287
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
382 KB
Volume
39
Category
Article
ISSN
1477-9226

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Three trinuclear complex anions, [(FeCi&hlS,]\*-(M = MO, \V) and [(MoS&Fe13; were studied by MBssbauer and magnetic measurements. The results imply a high electron affinity of the MS:-group and intramolecular spin coupling These properties and structural features suggest these molecular groups as po