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Extended analogues of tetrathiafulvalene (TTF): 1,2-bis, 1,4-bis and 1,2,4,5-tetrakis(1,4-dithiafulven-6-yl) benzenes; Synthesis and π-donor abilities.

✍ Scribed by Marc Salle; Ahmed Belyasmine; Alain Gorgues; Michel Jubault; Noël Soyer

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
283 KB
Volume
32
Category
Article
ISSN
0040-4039

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The synthesis of highly extended and sulfur rich tetrathiafulvalene derivatives, designed to avoid any internal cyclisation during their subsequent electrooxidation, is described. Their x-donating ability is confirmed by cyclic voltammetry, as well as the good stability of each of their oxidized spe

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Proximity effects in mass spectrometry. Electron impact ionization-induced cyclization of 1,2-bis(1,4-dithiafulven-6-yl)benzenes
✍ P. Frère; A. Gorgues; J. Garín; J. Orduna 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB

## Abstract The electron impact ionization mass spectra of __o__‐, __m__‐ and __p__‐bis(1,4‐dithiafulven‐6‐yl)benzenes were studied by means of accurate mass measurements, metastable analysis and collision‐induced dissociation. Differences observed in the spectra of the __ortho__ isomers are due to