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Exploring the Reactivity of C(sp3)-Cyclometalated IrIII Compounds in Hydrogen Transfer Reactions

✍ Scribed by Clarite Azerraf; Dmitri Gelman

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 280 KB
Volume: 14
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200801728

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✦ Synopsis

Abstract

The manuscript describes the synthesis and full characterization of a new PC(sp^3^)P‐based cyclometalated Ir^III^ complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C(sp^3^__)‐__metalated compounds.

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