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Exploring the Reactivity of Carbon(0)/Borane-Based Frustrated Lewis Pairs

✍ Scribed by Manuel Alcarazo; Catherine Gomez; Sigrid Holle; Richard Goddard

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
307 KB
Volume
122
Category
Article
ISSN
0044-8249

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Reactions of Amine– and Phosphane–Borane
Reactions of Amine– and Phosphane–Borane Adducts with Frustrated Lewis Pair Combinations of Group 14 Triflates and Sterically Hindered Nitrogen Bases
✍ George R. Whittell; Edward I. Balmond; Alasdair P. M. Robertson; Sanjib K. Patra 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 309 KB

The ability of trialkyl Group 14 triflates in combination with amine and pyridine bases to dehydrogenate amine-and phosphane-borane adducts has been investigated. By using multinuclear NMR spectroscopy, it has been shown that Me 2 NH•BH 3 ( ) is efficiently converted to [Me 2 N-BH 2 ] 2 ( ) by the s