Exploring the Limits of Branching and Gel Content in the Emulsion Polymerization of n -BA
✍ Scribed by González, Iñigo; Leiza, José R.; Asua, José M.
- Book ID
- 121856665
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 104 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The preparation of a series of poly(__n__‐butyl acrylate‐__co__‐acrylic acid) latexes with different contents of chain‐transfer agent are reported, and investigations into the adhesive properties of the latexes were made. The latexes were prepared at a solid content of 50 wt % by a two‐
bis [-[(2,3-butanedione dioximato)(2-)-O:OЈ]] tetrafluorodiborato(2-)-N, NЈ,NЉ,Nٞ] cobalt), CoBF, has been used for the effective catalytic chain transfer of alkyl methacrylate homo-and copolymers under emulsion polymerization conditions. The catalytic chain transfer process reduces the rate of poly