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Exploring a New, Connective Pummerer Reaction: Formation of Oxindoles by the Reaction of Thiols with Glyoxamides.

✍ Scribed by Marc Miller; William Tsang; Andrew Merritt; David J. Procter

Publisher
John Wiley and Sons
Year
2007
Weight
30 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

The Reaction of Cyanothioformamide with
The Reaction of Cyanothioformamide with Isocyanates βˆ’ Formation of a Disulfide by Reduction of a Thiocarbonyl Group
✍ Roger Ketcham; Ernst Schaumann; Gunadi Adiwidjaja πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 282 KB πŸ‘ 2 views

The reactions of the title compounds are governed by sulfur redox chemistry. Thus, cyanothioformamide 2 reacts with aryl isocyanates 3a-c to give bis[3-aryl-1-(arylcarbamoyl)-2oxo-4-(arylcarbamoylimino)imidazolidin-5-yl] disulfides 6, as shown by an X-ray crystallographic investigation of product 6a