Exploiting time-reversal symmetry in lig
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Mark J. Riley
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Article
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1991
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Elsevier Science
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English
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It is shown that for all point groups which contain Cz or C, as an invariant subgroup, the ligand-field eigenvalue problem for odd-electron systems can be reduced to half the size. The procedure is a consequence of the way the eigenfunctions transform under time reversal.