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Explanation of Deuterium and Muonium Kinetic Isotope Effects for Hydrogen Atom Addition to an Olefin

✍ Scribed by Villà, Jordi; Corchado, José C.; González-Lafont, Angels; Lluch, José M.; Truhlar, Donald G.

Book ID
127059281
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
31 KB
Volume
120
Category
Article
ISSN
0002-7863

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Secondary α-deuterium kinetic isotope ef
Secondary α-deuterium kinetic isotope effects for addition of phenyl radical to benzyl isocyanides: An evidence of concerted mechanism.
✍ Soo Kim Sung; Seung Lee Ki; Bong Hwang Soo; Jin Kim Hee 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 282 KB

Sumnary: Addition of phenyl radical to benzyl isocyanides gives benzonitrile and benzyl radicals, exhibiting positive Hamnett p=O.26 and notable secondary a-deuterium kinetic isotope effects. These can be rationalized by concerted bond formation/cleavage occurring with polar transition states(TS).