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Experiments with soap-free polymerization of styrene in the presence of alcohols

โœ Scribed by A. M. Homola; M. Inoue; A. A. Robertson


Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
412 KB
Volume
19
Category
Article
ISSN
0021-8995

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โœฆ Synopsis


Abstract

Polystyrene latexes have been synthesized by a method based on that Kotera et al.^4^ The polymerization rates and yields have been improved by the addition of an alcohol (methanol) to the reactants. The effects of varying the methanol content and other process variables on the polymerization and on the properties of the latex are reported.


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Radical polymerizations of styrene in the presence of C 60 have been conducted at 90ยฐC in benzene using benzoyl peroxide (BPO) as initiator. The behaviors of C 60 are investigated by monitoring BPO concentration, C 60 content, and polymerization time. It is found that C 60 acts like a radical absorb