The interpretation of pressure-dependent
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Robert G. Gilbert; Brendan J. Gaynor; Keith D. King
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Article
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1979
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John Wiley and Sons
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English
β 854 KB
## Abstract Unimolecular rate data from systems such as veryβlowβpressure pyrolysis (steadyβstate flow) and static experiments where gasβgas collisions compete with gasβwall collisions must be interpreted in terms of reactant inhomogeneity arising from finite diffusion rates, rather than using the