Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for
Experimental study of the reactions of N2(A 3Σ+u) with H atoms and OH radicals
✍ Scribed by Ho, Grace H.; Golde, Michael F.
- Book ID
- 115545906
- Publisher
- American Institute of Physics
- Year
- 1991
- Tongue
- English
- Weight
- 668 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.461219
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reactions of 0( 'P) atoms with CH,OH and CH,CHOH have been measured directly for the first time. In a discharge flow reactor CH,OH/CH,CHOH profiles were monitored at ambient temperature and in an excess of 0 atoms by a mass spectrometer, working at low electron energies. The effect of subsequent
## Abstract The mechanisms and dynamics studies of the OH radical and Cl atom with CF~3~CHClOCHF~2~ and CF~3~CHFOCHF~2~ have been carried out theoretically. The geometries and frequencies of all the stationary points are optimized at the B3LYP/6‐311G(d,p) level, and the energy profiles are further
The reactions of N,O with NO and OH radicals have been studied using ab initio molecular orbital theory The energetics and molecular parameters, calculated by the modified Gaussian-2 method ( G 2 M ) . have been used to compute the reaction rate constants on the basis of the TST and RRKM theories Th