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Experimental Study of the Rate of OH + HO 2 → H 2 O + O 2 at High Temperatures Using the Reverse Reaction

✍ Scribed by Hong, Zekai; Vasu, Subith S.; Davidson, David F.; Hanson, Ronald K.


Book ID
118007197
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
295 KB
Volume
114
Category
Article
ISSN
1089-5639

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Rate constants of the reaction HO+H2O2→H
✍ H. Hippler; J. Troe 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 449 KB

HO2 profiles in the thermal decomposition of H,02 in shock waves over the range 1000-1250 K were analyzed with respect to the reactions HO+HZOz+HOz+H20 (3) and HO+H0r~Hz0+02 (4). Reaction (3) shows a strong up-turn ofthe rate constant at temperatures near 800 K. Over the range 250-1250 K, k, can be

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✍ Venkatesh Vasudevan; David F. Davidson; Ronald K. Hanson 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 244 KB 👁 2 views

## Abstract The reaction of hydroxyl [OH] radicals with formaldehyde [CH~2~O] was studied at temperatures ranging from 934 K to 1670 K behind reflected shock waves at an average total pressure of 1.6 atm. OH radicals were produced by shock‐heating tert‐butyl hydroperoxide [(CH~3~)~3~COOH], while