Experimental Study of the Rate of OH + HO 2 → H 2 O + O 2 at High Temperatures Using the Reverse Reaction
✍ Scribed by Hong, Zekai; Vasu, Subith S.; Davidson, David F.; Hanson, Ronald K.
- Book ID
- 118007197
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 295 KB
- Volume
- 114
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
HO2 profiles in the thermal decomposition of H,02 in shock waves over the range 1000-1250 K were analyzed with respect to the reactions HO+HZOz+HOz+H20 (3) and HO+H0r~Hz0+02 (4). Reaction (3) shows a strong up-turn ofthe rate constant at temperatures near 800 K. Over the range 250-1250 K, k, can be
## Abstract The reaction of hydroxyl [OH] radicals with formaldehyde [CH~2~O] was studied at temperatures ranging from 934 K to 1670 K behind reflected shock waves at an average total pressure of 1.6 atm. OH radicals were produced by shock‐heating tert‐butyl hydroperoxide [(CH~3~)~3~COOH], while