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Experimental studies on photodissociation of HI in crystalline xenon

โœ Scribed by W. Lawrence; F. Okada; V.A. Apkarian


Book ID
103025536
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
479 KB
Volume
150
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The photodissociation of HI at 277 nm in crystalline xenon is followed by monitoring the Xe,I exciplexic emission. Above 110 K, the product I atoms diffuse and recombine as 12. Between 110 and 80 K dissociation is permanent, and diffusion of I atoms is halted. Below 80 K amorphization ofthe solid is observed. The inclusion crystals are grown from the melt. Crystallinity is verified by the exciplexic lineshift.


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Thermodynamics is a well-established discipline of physics for properties of matter in thermal equilibrium with the surroundings. Applying to crystals, however, the laws encounter undefined properties of crystal lattice, which therefore need to be determined for a clear and well-defined description