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Experimental Studies of the Interconversion of μ-η 2 :η 2 -Peroxo- and Bis(μ-oxo)dicopper Complexes

✍ Scribed by Cahoy, John; Holland, Patrick L.; Tolman, William B.

Book ID
125995868
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
116 KB
Volume
38
Category
Article
ISSN
0020-1669

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Dioxygen activation by copper sites: rel
Dioxygen activation by copper sites: relative stability and reactivity of (μ-η2:η2-peroxo)- and bis(μ-oxo)dicopper cores
✍ Patrick L. Holland; William B. Tolman 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 310 KB

Investigations of complexes comprising the title cores are summarized with a view toward understanding their interconversion and possible implications in metallobiochemistry. Detailed studies on the solvent and concentration dependence of the equilibrium between (m-h 2 :h 2 -peroxo)dicopper(II) (A)