Rarkee-Fock, energy curves have been calculated for the X2tI a.nd 2Z\*states of HP and applied to an analysis. of the photoelectron spectra of HF. The 2$+ energy curve is found to have a barrier about 0.07 eV high due primarily
Experimental potential energy curves for X2Π and 2Σ+ states of HF+
✍ Scribed by J. Berkowitz
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 682 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Introduction taneously. The HP and DF* peaks are distinctly broader than the Ar peaks, and incipient splitting can The preceding paper [I J has presented a purely be se-en in some of the DF+ peaks. 'This is attributed theoretical (Hartree-Fock) calculation of the X*IYI to the *l-I,,,-*lI a,* spl,itting LIZ HFf . An enlarged and 2Zc potential energy curves of HF+, and the vibracume of DF+ taken with the 735.895 A line of Ne is tional levels deduced therefrom. it seems appropriate shown in fig. 2. Some evidence of a triplet structure at this time to present new experimental information can be seen. It was evidenced in several successive ex-.. :. ., ment& &,,+I 2 I,z $itting of approximately ,' ;. 30 MeV. Richkds and .WiI&n [3]-have &mated the VoIume.11, number 1 CKEhIKALPHr~ICS LETTERS
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