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Experimental observation of autoionizing transitions from the decay of the 1,3Πu inner-shell excited states of carbon dioxide

✍ Scribed by D.P. Almeida; G. Dawber; G.C. King


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
306 KB
Volume
233
Category
Article
ISSN
0009-2614

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✦ Synopsis


Inner-shell excited states of carbon dioxide have been studied in a high-resolution electron impact experiment. The excited states (Is) -~(2p~r,) ~'317 u have been observed as a function of impact energy via their decay, by ejection of an electron, to an ionic state of the molecule. A shift in the energies of these ejected electrons has been observed and is explained in terms of a post collision interaction effect. The relative cross section for the formation of the CO~ (A 217,) final ionic state, via the decay of these inner-shell excited states, has been measured.