Orbital relaxation in the Rydberg series
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Tse-Chiang Chang
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Article
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1983
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John Wiley and Sons
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English
โ 323 KB
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Self-consistent-field (SCF) calculations for a series of Rydberg states (ls2ns)2S of the Li atom are performed using the generalized Brillouin theorem (GBT) method. The calculated energy is a proper upper bound to the excited state energy. The SCF term values of the Rydberg states are almost the sam