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Experimental measurements of self-heating in the explosive decomposition of diethyl peroxide

โœ Scribed by D.H. Fine; Peter Gray; R. Mackinven


Book ID
108392948
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
823 KB
Volume
12
Category
Article
ISSN
1540-7489

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Ignition, self-heating, and the effects
โœ John F. Griffiths; Jeremy R. Mullins ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 922 KB

The thermal decomposition of di-tertiary-butyl peroxide vapor is exothermic, and, in a closed vessel, the resultant self-heating may lead to ignition. The parameters that determine the criteria for ignition are encapsulated in Frank-Kamenetskii's 6, and they include exothetrnicity and Arrhenius cons