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Experimental investigations of the electrolysis of D2O using palladium cathodes and platinum anodes

✍ Scribed by Lance L. Zahm; Andrew C. Klein; Stephen E. Binney; José N. Reyes Jr.; Jack F. Higginbotham; Alan H. Robinson; Malcolm Daniels; Richard B. Peterson

Publisher
Elsevier Science
Year
1990
Weight
604 KB
Volume
281
Category
Article
ISSN
0022-0728

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EPR study has shown that the anticancer agent vanadocene dichloride (Cp2VCl2) interacts with carbonate contained in physiological solutions. Chelate complex Cp2VO2CO (|A(iso)(51V)| = 175.1 MHz, g(iso) = 1.9861) is the only paramagnetic species formed in the range about the physiological pH (5.5-11.0