Experimental investigation and thermodynamic assessment of the Al-rich side of the Al–B system

✍ Scribed by Jonas Fjellstedt; Anders E.W. Jarfors; Talaat El-Benawy

• Book ID: 104313610
• Publisher: Elsevier Science
• Year: 2001
• Weight: 398 KB
• Volume: 22
• Category: Article
• ISSN: 0261-3069
• DOI: 10.1016/s0261-3069(00)00076-5

✦ Synopsis

The phase relations in the Al᎐Ti᎐B system are of great importance for the manufacturing of AlrTiB composites. To describe 2 the phase relations, the relations in the binaries Al᎐B, Ti᎐B and Al᎐Ti must be known. The description of the binary Al᎐B system has been found to be poor. The Al-rich side of the Al᎐B phase diagram was studied using DSC, on alloys ranging from 0.5 up to 6.4 at.% B. The Al-rich part of the phase diagram was assessed using the experimental data and data found in the literature. The eutectic temperature was found to agree well with the literature. However, the peritectic temperature was found to be 914ЊC. Above the peritectic temperature a metastable primary precipitation of AlB below the AlB liquidus line was 2 1 2

suggested. This type of degenerate peritectic reaction is similar to what has been found in Fe-based materials. This behaviour also explains the difficulty in the determination of the peritectic point by experimental means.