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Experimental Evidence of Conformational Differences between C -Glycosides and O -Glycosides in Solution and in the Protein-Bound State: The C -Lactose/ O -Lactose Case

✍ Scribed by Espinosa, Juan-Félix; Cañada, F. Javier; Asensio, Juan Luis; Martín-Pastor, Manuel; Dietrich, Hansjörg; Martín-Lomas, Manuel; Schmidt, Richard R.; Jiménez-Barbero, Jesús


Book ID
126884819
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
324 KB
Volume
118
Category
Article
ISSN
0002-7863

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Conformational difference in the solid s
✍ Masataka Mori; Tatsuji Chuman; Takane Fujimori; Kunio Kato; Akira Ohkubo; Shozo 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 479 KB

The conformational difference of the title compound (1) in the solid state and in solution has been investigated by X-ray crystallography and high-field proton n.m.r. spectrometry. In the solid state, compound 1 adopts the "c,(D) conformation (la), whereas 1 exists preferentially in the 'C4(D) confo