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Experimental evidence for the gas phase existence of HSOH (hydrogen thioperoxide) and SOH2 (thiooxonium ylide)

โœ Scribed by Muhammad Iraqi; Helmut Schwarz

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
326 KB
Volume
221
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Experiments are reported on the successful gas phase generation of hydrogen thioperoxide (HSOH ) and thiooxonium ylide (SOHz).

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Stable [C2H7O2]+ isomers: Experimental a
Stable [C2H7O2]+ isomers: Experimental and theoretical evidence for the existence of protonated peroxides and proton-bound dimers in the gas phase
โœ Jan H. van Driel; Wigger Heerma; Johan K. Terlouw; Herman Halim; Helmut Schwarz ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 703 KB

Evidence is presented for the gas phase generation of at least eight stable isomeric [C,H,O,]' ions. These include energy-rich protonated peroxides (ions CH,CHz06H, (e), CH3CH,6(H)OH (f) and CH,06(H)CH3(g)), proton-bound dimers (ions CH3CH=0 --k -OHz ( h ) and CH, O \* \* \* HOCH3 ( i ) ) and hydrox