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Experimental determination of the electron tunneling probability as a function of distance for chemical reactions

✍ Scribed by K.I. Zamaraev; R.F. Khairutdinov; J.R. Miller

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 364 KB
Volume: 57
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)80458-8

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✦ Synopsis

The !cinetics for the tunneling reaction of trapped electrons with Cu(en)$+ in a rigid. glassy matrix at 77 K have been measured using pulse radiolysis. The distriiution of the Cu(e& k ions was studied in &e same system by measurements of ESR line widths, and found to be uniform (random). These measurements help to confii the measured tunneIing distances and the exponential dependence of the raates on the distance between the ekctron donor and acceptor.

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