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Experimental Detection of Tetraoxygen

✍ Scribed by Fulvio Cacace; Giulia de Petris; Anna Troiani


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
105 KB
Volume
40
Category
Article
ISSN
0044-8249

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✦ Synopsis


Although suggested by Lewis in 1924 and theoretically predicted, O has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O species. The search has now been brought to an end by the conclusive proof, achieved by neutralization-re-ionization mass spectrometry, of the existence of intact O as a gas-phase species with a lifetime in excess of 1 ΞΌs, whose dissociation requires overcoming a barrier of the order of 10 kcal mol .


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