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Experimental assessment of the phonon confinement in TiO2 anatase nanocrystallites by Raman spectroscopy

✍ Scribed by Dumitru Georgescu; Lucian Baia; Ovidiu Ersen; Monica Baia; Simion Simon


Book ID
112134779
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
662 KB
Volume
43
Category
Article
ISSN
0377-0486

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We present a comprehensive analysis of the Raman spectra of pure and zirconium-doped anatase TiO 2 nanoparticles. To account for the wavenumber shifts of the E g (Ξ½ 6 ) mode as a function of particle size (L) and dopant concentration (x), a modification of the standard phonon confinement model (PCM)