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Experimental and Theoretical Study of the Keto–Enol Tautomerization of 3,5-Dioxopimelates

✍ Scribed by Silke Erfle; Stefanie Reim; Dirk Michalik; Haijun Jiao; Peter Langer


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
179 KB
Volume
2011
Category
Article
ISSN
1434-193X

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📜 SIMILAR VOLUMES


N.m.r. studies of the keto–enol tautomer
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## Abstract Acetylthioacetamides exist as different keto and enol isomers in chloroform solutions. The keto form with intramolecular hydrogen bonding between the NH and the carbonyl group is the dominant keto isomer. On the other hand the enol forms with intramolecular hydrogen bonding between the

The keto–enol tautomerization of ethyl b
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## Abstract The keto–enol tautomerism of ethyl butylryl acetate was studied in mixed solvents under a variety of experimental conditions. The direct measurement of ketonization of the enol tautomer was performed by using the hyphenated technique LC‐NMR. The keto and enol tautomers can be separated

The enol-imine to keto-enamine tautomeri
✍ E. J. Kikta Jr; J. F. Bieron 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 624 KB

## Abstract The formation of 3‐benzylamino‐5,5‐dimethylcyclohex‐2‐enone has been found to proceed through the initial formation of its enol‐imine tautomer. The enol‐imine has been isolated by a novel synthesis. It involves suspending dimedone in hexane for one hour at 67 °C with the amine in soluti