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Experimental and theoretical study of the intramolecular C-H···N and C-H···S hydrogen bonding effects in the 1 H and 13 C NMR spectra of the 2-(alkylsulfanyl)-5-amino-1-vinylpyrroles: a particular state of amine nitrogen

✍ Scribed by Afonin, Andrei V.; Pavlov, Dmitry V.; Albanov, Alexander I.; Tarasova, Ol'ga A.; Nedolya, Nina A.

Book ID
120533023
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
515 KB
Volume
51
Category
Article
ISSN
0749-1581

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📜 SIMILAR VOLUMES

CH···N and CH···O intramolecular hydroge
CH···N and CH···O intramolecular hydrogen bonding effects in the 1H, 13C and 15 N NMR spectra of the configurational isomers of 1-vinylpyrrole-2-carbaldehyde oxime substantiated by DFT calculations
✍ Andrei V. Afonin; Igor A. Ushakov; Alexander V. Vashchenko; Dmitry E. Simonenko; 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB

## Abstract According to the ^1^H, ^13^C and ^15^N NMR spectroscopic data and DFT calculations, the __E__‐isomer of 1‐vinylpyrrole‐2‐carbaldehyde adopts preferable conformation with the __anti__‐orientation of the vinyl group relative to the carbaldehyde oxime group and with the __syn__‐arrangement