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Experimental and theoretical study of the influence of pressure on SCWO

✍ Scribed by M. D. Bermejo; I. Bielsa; M. J. Cocero

Publisher
American Institute of Chemical Engineers
Year
2006
Tongue
English
Weight
335 KB
Volume
52
Category
Article
ISSN
0001-1541

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✍ M. Kotani; Y. Shigetomi; M. Imada; M. Ōki; M. Nagaoka πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 231 KB πŸ‘ 1 views

The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr