Experimental and Theoretical Studies on the Thermal Decomposition of Heterocyclic Nitrosimines1
β Scribed by Bartsch, Richard A.; Chae, Yeh Moon; Ham, Sihyun; Birney, David M.
- Book ID
- 115514690
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 246 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
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## Abstract Thermal pyrolysis of halon 1211 (CBrClF~2~), diluted in nitrogen, in a tubular alumina reactor, has been studied over the temperature range of 773β1073 K at residence times from 0.3 to 2 s. At temperatures below 973 K, the major products were CCl~2~F~2~, CBr~2~F~2~, C~2~Cl~2~F~4~, C~2~B