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Experimental and Theoretical Studies on Some Energetic Functionalized Trimethylamine Derivatives

✍ Scribed by Thomas M. Klapötke; Burkhard Krumm; Matthias Scherr; F. Xaver Steemann; Klaus Banert; Young-Hyuk Joo

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
354 KB
Volume
15
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

The synthesis and structural properties (from X‐ray diffraction or B3LYP/6‐31G(d) calculations) of three energetic compounds derived from tris(chloromethyl)amine and of tris(chloromethyl)amine itself were investigated and compared to those of compounds with similar structures. The compounds have almost planar NC~3~ units at their amine center, and the substituents bound to the CH~2~ groups tend to be reactive towards further substitution. Multiple hyperconjugation was used to explain these observations.

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