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Experimental and theoretical studies of the gas-phase protonation of vinyl ethers, vinyl sulfides, and vinyl selenides

✍ Scribed by Osapay, K.; Delhalle, J.; Nsunda, K. M.; Rolli, E.; Houriet, R.; Hevesi, L.


Book ID
126117864
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
975 KB
Volume
111
Category
Article
ISSN
0002-7863

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A DFT proton affinity study of vinyl and
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Proton affinities of vinyl and allyl anions of cyclic vinyl ethers and cycloalkenes obtained at the B3PW91 level with Davidson's modification of basis set aug-cc-pVDZ are presented to further explore deprotonation reactions of cyclic vinyl ethers. The presence of an oxygen atom Β’x to a vinyl anion h