Experimental and Theoretical Studies of SiF n (CO) 2+ Cations with n = 2 and 3: A Search for Pentacoordinate Cationic Silicon
β Scribed by Ketvirtis, A. E.; Baranov, V. I.; Hopkinson, A. C.; Bohme, D. K.
- Book ID
- 120313242
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 241 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
The structure and binding energies are determined for M&CO,).+ and Sr(CO,),' for n= 1 and 2. We also consider Mg: and Mg#ZO: to compare the binding of CO1 to a single metal ion with the binding to a diatomic ion. The vertical excitation energies are computed for all species. The potential energy cur
Two bis-flavine derivatives linked by a 1,3-diamidobenzene and a 1,3-diamidopyridine have been prepared and their conformation determined by a combination of NMR experiments ( 1 H and 13 C) and DFT calculations including GIAO absolute shieldings. In the case of the pyridyl derivative, the conformati