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Experimental and theoretical investigations of the reactions NH(X [sup 3]Σ[sup −])+D([sup 2]S)→ND(X [sup 3]Σ[sup −])+H([sup 2]S) and NH(X [sup 3]Σ[sup −])+D([sup 2]S)→N([sup 4]S)+HD(X [sup 1]Σ[sub g][sup +])

✍ Scribed by Qu, Z.-W.; Zhu, H.; Schinke, R.; Adam, L.; Hack, W.


Book ID
111962994
Publisher
American Institute of Physics
Year
2005
Tongue
English
Weight
422 KB
Volume
122
Category
Article
ISSN
0021-9606

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.