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Experimental and Theoretical Evidence for Oxirane Formation Reaction of Pentacoordinate 1,2λ 6 -Oxathietanes with Retention of Configuration

✍ Scribed by Kawashima, Takayuki; Ohno, Fumihiko; Okazaki, Renji; Ikeda, Hirotaka; Inagaki, Satoshi

Book ID: 126788077
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 212 KB
Volume: 118
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja9629975

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ChemInform Abstract: Novel Reactivity of

ChemInform Abstract: Novel Reactivity of Tetracoordinate 1,2λ4-Oxaselenetanes: Oxirane Formation Reaction with Retention of Configuration.

✍ F. OHNO; T. KAWASHIMA; R. OKAZAKI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

The title reaction represents the first oxirane formation (cf. (IX) and (XII)) from tetracoordinate oxaselenetanes, e.g. (VIII) and (XI). Retention of configuration is observed in the case of (XI). -(OHNO, F.;