Experimental and theoretical electron density analysis of metal-metal bonding in dichromium tetraacetate
โ Scribed by Benard, M.; Coppens, P.; DeLucia, M. L.; Stevens, E. D.
- Book ID
- 120248670
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 848 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m
The nature of the quadruple metal-metal bond for MMo(O&H)., (M=Mo, Cr), and Mo~X~(PH~)~ (X=CI, Br, I) complexes, was investigated using the Bader theory and relativistic pseudopotentials. The topological results show that the direct metal-metal interaction is dominated by a strong charge depletion a