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Experimental and Theoretical Conformational Analysis of Methylene- and Cyanophosphines and Their Oxides

✍ Scribed by Yana A. Vereshchagina; Vladimir E. Kataev; Eleonora A. Ishmaeva; Gulnaz R. Fattakhova; Alexander V. Kataev; Arkadiy N. Pudovik

Publisher
John Wiley and Sons
Year
2003
Weight
51 KB
Volume
34
Category
Article
ISSN
0931-7597

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AMI calculations show 2-nitraminopyridine to contain 97.7 % of 1,2-dihydro-2-nitriminopyridine form which was found to be the most stable in the gas phase. Except the proton transfer processes, dimerizafion was also found to appear in this compound. Instead, non-planar nilyamine form was found to do