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Experimental and Theoretical Analysis of the Kinetics of the Reaction of Atomic Bromine with 1,4-Dioxane

✍ Scribed by Giri, Binod Raj; Roscoe, John M.; González-García, Núria; Olzmann, Matthias

Book ID
127157486
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
196 KB
Volume
114
Category
Article
ISSN
1089-5639

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✍ Toshitsugu Yokota; Richard B. Timmons 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 462 KB 👁 1 views

The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637°K. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius