𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Experimental and modeling study of the oxidation of 1-pentene at high temperature

✍ Scribed by S. Touchard; F. Buda; G. Dayma; P. A. Glaude; R. Fournet; F. Battin-Leclerc

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
165 KB
Volume
37
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Ignition delay times of 1‐pentene–oxygen–argon mixtures have been measured behind shock wave, the onset of ignition being detected by OH radical emission. Mixtures contained 1 or 2% of hydrocarbon for equivalence ratios ranging from 0.5 to 2. Reflected shock waves allowed temperatures from 1130 to 1620 K and pressures from 7.3 to 9.5 atm to be obtained. A detailed mechanism of combustion of 1‐pentene has been automatically generated using EXGAS software. This mechanism has been validated by comparing the results of the simulations to the experimental ignition delay times. The main reaction pathways have been derived from flow rate and sensitivity analyses at different temperatures. Comparisons with 1‐butene and 1‐hexene in the same conditions show that 1‐pentene has a higher reactivity which seems to be due to its decomposition to give ethyl radicals, which rapidly yields very reactive hydrogen atoms, while the decomposition of 1‐butene and 1‐hexene leads to less reactive methyl radicals. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 37: 451–463, 2005

📜 SIMILAR VOLUMES

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of isobutene
✍ J. C. Bauge; F. Battin-Leclerc; F. Baronnet 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 2 views

This article describes an experimental and modeling study of the oxidation of isobutene. The low-temperature oxidation was studied in a continuous-flow stirred-tank reactor operated at constant temperature (from 833 to ) and pressure with fuel 913 K (1 atm), equivalence ratios from 3 to 6 and spac

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of toluene
✍ R. Bounaceur; I. Da Costa; R. Fournet; F. Billaud; F. Battin-Leclerc 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB 👁 1 views

## Abstract This paper describes an experimental and modeling study of the oxidation of toluene. The low‐temperature oxidation was studied in a continuous flow stirred tank reactor with carbon‐containing products analyzed by gas chromatography under the following experimental conditions: temperatur

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of cyclohexene
✍ G. Dayma; P. A. Glaude; R. Fournet; F. Battin-Leclerc 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 231 KB

## Abstract Ignition delays of cyclohexene–oxygen–argon mixtures were measured behind shock. Mixtures contained 1 or 2% of hydrocarbons for equivalence ratios ranging from 0.5 to 2. Reflected shock waves permitted to obtain temperatures from 1050 to 1520 K and pressures from 7.7 to 9.1 atm. The exp

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of benzene
✍ I. Da Costa; R. Fournet; F. Billaud; F. Battin-Leclerc 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 484 KB 👁 1 views

## Abstract This paper describes an experimental and modeling study of the oxidation of benzene. The low‐temperature oxidation was studied in a continuous flow stirred tank reactor with carbon‐containing products analyzed by gas chromatography. The following experimental conditions were used: 923 K

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of 1-butyne and 2-butyne
✍ N. Belmekki; P. A. Glaude; I. Da Costa; R. Fournet; F. Battin-Leclerc 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

## Abstract Ignition delays were measured behind shock waves in the cases of hydrocarbon–oxygen–argon mixtures containing 1‐butyne or 2‐butyne (1 or 2% of hydrocarbons for equivalence ratios from 0.5 to 2). Reflected shock waves permitted to obtain temperatures from 1100 to 1600 K and pressures fro