𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Experimental and modeling study of the autoignition of cyclopentene

✍ Scribed by M. Yahyaoui; M. H. Hakka; P. A. Glaude; F. Battin-Leclerc

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
376 KB
Volume
40
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Ignition delay times of cyclopentene–oxygen–argon mixtures were measured behind reflected shock waves. Mixtures contained 0.5% or 1% of hydrocarbons for equivalence ratios ranging from 0.5 to 1.5. Reflected shock wave conditions were as follows: temperatures from 1300 to 1700 K and pressures from 7 to 9 atm. When compared with the previous results obtained under similar conditions, it can be observed that the reactivity of cyclopentene is much lower than that of cyclohexene, but very close to that of cyclopentane. A kinetic mechanism recently proposed for the combustion of cyclopentene in a flame has been used to model these results, and a satisfactory agreement is obtained. The main reaction pathways have been derived from the flow rate, simulated temporal profiles of products, and sensitivity analyses. Β© 2007 Wiley Periodicals, Inc. Int J Chem Kinet 40: 25–33, 2008

πŸ“œ SIMILAR VOLUMES

Experimental and modeling study of oxida
Experimental and modeling study of oxidation and autoignition of butane at high pressure
✍ R. Minetti; M. Ribaucour; M. Carlier; C. Fittschen; L.R. Sochet πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 739 KB

Oxidation and autoignition of stoichiometric, lean (q~ = 0.8), and rich (q~ = 1.2)butane-"air" mixtures are studied in a rapid compression machine between 700-900 K and 9-11 bar. Information is obtained concerning cool flames and ignition delays. Product profiles for selected major and minor species

Autoignition of heptanes; experiments an
Autoignition of heptanes; experiments and modeling
✍ John M. Smith; John M. Simmie; Henry J. Curran πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 121 KB

## Abstract There is much interest in determining the influence of molecular structure on the rate of combustion of hydrocarbons; the C~7~H~16~ isomers of heptane have been selected here as they exemplify all the different structural elements present in aliphatic, noncyclic hydrocarbons. With the

An experimental and theoretical study of
An experimental and theoretical study of autoignition on a horizontal hot pipe
✍ A.J. Harrison; R.M. Furzeland; R. Summers; L.R. Cairnie πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 607 KB

A mathematical model has been formulated which describes the initiation of acetaldehyde cool flames in the free convection boundary layer adjacent to a horizontal hot pipe. The model accurately predicts the experimentally determined boundary layer temperature profiles in the case of nonreacting flow

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of isobutene
✍ J. C. Bauge; F. Battin-Leclerc; F. Baronnet πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 210 KB πŸ‘ 2 views

This article describes an experimental and modeling study of the oxidation of isobutene. The low-temperature oxidation was studied in a continuous-flow stirred-tank reactor operated at constant temperature (from 833 to ) and pressure with fuel 913 K (1 atm), equivalence ratios from 3 to 6 and spac

Experimental and modeling study of the o
Experimental and modeling study of the oxidation of toluene
✍ R. Bounaceur; I. Da Costa; R. Fournet; F. Billaud; F. Battin-Leclerc πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 404 KB πŸ‘ 1 views

## Abstract This paper describes an experimental and modeling study of the oxidation of toluene. The low‐temperature oxidation was studied in a continuous flow stirred tank reactor with carbon‐containing products analyzed by gas chromatography under the following experimental conditions: temperatur