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Experimental and Computational Studies on the Mechanism of N -Heterocycle C−H Activation by Rh(I)

✍ Scribed by Wiedemann, Sean H.; Lewis, Jared C.; Ellman, Jonathan A.; Bergman, Robert G.


Book ID
120350470
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
314 KB
Volume
128
Category
Article
ISSN
0002-7863

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The dual-level direct kinetics method has been used to investigate the multichannel reactions of C(2)H(5)I + Cl. Three hydrogen abstraction channels and one displacement process are found for the title reaction. The calculation indicates that the hydrogen abstraction from -CH(2)- group is the domina